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x-T phase diagram of La-substituted BiFeO3-PbTiO3
2. J. J. Wang, J. B. Neaton, H. Zheng, V. Nagarajan, S. B. Ogale, B. Liu, D. Viehland, V. Vaithyanathan, D. G. Schlom, U. V. Waghmare, N. A. Spaldin, K. M. Rabe, M. Wuttig, R. Ramesh, Science 299, 1719 (2003).
18. K. K. Mishra et al. (2011) unpublished.
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Single-phase polycrystallinepowders of 0.5(Bi1- x La x )FeO3-0.5PbTiO3 solid-solution were synthesized for x ≤ 0.3 using solid-state reaction method. The mixed crystals exhibit a tetragonal structure at ambient and the c/a ratio decreases with x. In-situX-ray diffraction measurements at elevated temperatures show a structural transition to a cubic phase. The transition temperatures have been obtained for different x and a x-Tphase diagram has been proposed.
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