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Observation of high pressure o-GeTe phase at ambient pressure in Si-Te-Ge glasses
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Te-rich Si15Te85-xGex (1 ≤ x ≤ 11) glasses are found to exhibit an anomalous phase separations with germanium composition. The structural transformation of o-GeTe crystalline phase from o-GeTe with a = 11.76 Å, b = 16.59 Å, c = 17.44 Å, to high pressureo-GeTe with a new reduced lattice parameters a = 10.95 Å, b = 4.03 Å, c = 4.45 Å, is observed at Tc3 in the composition range 6 ≤ x ≤ 11. Raman studies support the possible existence of high pressureo-GeTe phase which is observed in X-ray diffraction experiments.
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