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Flexible solid-state symmetric supercapacitor was fabricated using MnO nanofilms growing directly on carbon cloth as the electrodes and PVA/HPO gel as the electrolyte/separator. The device can be operated at a stable cell-voltage up to 1.4 V, obviously larger than that of conventional solid-state symmetric supercapacitors (≤1 V). It exhibited excellent rate capability with a scan rate as high as 20 V s and a long cyclability (∼60000 cycles) even under severe mechanical deformation. The charge storage mechanism at different scan rates was also quantitatively analyzed.


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