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/content/aip/journal/adva/4/1/10.1063/1.4863092
2014-01-23
2015-07-07

Abstract

We report on the reduction of band gap in Bi (Na LiK)(TiSn)O from 2.99 eV to 2.84 eV due to the substitutions of Li+ ions to Na + sites. In addition, the lithium substitution samples exhibit an increasing of the maximal polarizations from 21.8 to 25.7 μC/cm2. The polarization enhancement of ferroelectric and reduction of the band gaps are strongly related to the Li substitution concentration as evaluated via the electronegative between A-site and oxygen and tolerance factor. The results are promising for photovoltaic and photocatalytic applications.

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Scitation: Band gap modification and ferroelectric properties of Bi0.5(Na,K)0.5TiO3-based by Li substitution
http://aip.metastore.ingenta.com/content/aip/journal/adva/4/1/10.1063/1.4863092
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