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A physical interpretation of impedance at conducting polymer/electrolyte junctions
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1.
1. J. M. Leger, Adv. Mater. 20 (4), 837841 (2008).
http://dx.doi.org/10.1002/adma.200701874
2.
2. J. Leger, M. Berggren, and S. A. Carter, Iontronics : Ionic carriers in organic electronic materials and devices. (CRC Press, Boca Raton, 2011).
3.
3. Q. Pei, G. Yu, C. Zhang, Y. Yang, and A. J. Heeger, Science 269 (5227), 10861088 (1995).
http://dx.doi.org/10.1126/science.269.5227.1086
4.
4. J. C. deMello, N. Tessler, S. C. Graham, and R. H. Friend, Physical Review B 57 (20), 1295112963 (1998).
http://dx.doi.org/10.1103/PhysRevB.57.12951
5.
5. D. A. Bernards, S. Flores-Torres, H. D. Abruna, and G. G. Malliaras, Science 313 (5792), 14161419 (2006).
http://dx.doi.org/10.1126/science.1128145
6.
6. R. J. Mortimer, A. L. Dyer, and J. R. Reynolds, Displays 27(1), 218 (2006).
http://dx.doi.org/10.1016/j.displa.2005.03.003
7.
7. H. D. Abruna, Y. Kiya, and J. C. Henderson, Physics Today 61(12), 4347 (2008).
http://dx.doi.org/10.1063/1.3047681
8.
8. D. Khodagholy, J. Rivnay, M. Sessolo, M. Gurfinkel, P. Leleux, L. H. Jimison, E. Stavrinidou, T. Herve, S. Sanaur, R. M. Owens, and G. G. Malliaras, Nat Commun 4 (2013).
http://dx.doi.org/10.1038/ncomms3133
9.
9. E. Smela, MRS Bull. 33(3), 197204 (2008).
http://dx.doi.org/10.1557/mrs2008.45
10.
10. J. Rivnay, R. M. Owens, and G. G. Malliaras, Chemistry of Materials (2013).
11.
11. J. Isaksson, P. Kjall, D. Nilsson, N. D. Robinson, M. Berggren, and A. Richter-Dahlfors, Nat. Mater. 6(9), 673679 (2007).
http://dx.doi.org/10.1038/nmat1963
12.
12. P. Lin and F. Yan, Adv. Mater. 24(1), 3451 (2012).
http://dx.doi.org/10.1002/adma.201103334
13.
13. D. Khodagholy, T. Doublet, P. Quilichini, M. Gurfinkel, P. Leleux, A. Ghestem, E. Ismailova, T. Hervé, S. Sanaur, C. Bernard, and G. G. Malliaras, Nat Commun 4, 1575 (2013).
http://dx.doi.org/10.1038/ncomms2573
14.
14. A. Elschner, S. Kirchmeyer, W. Lövenich, U. Merker, and K. Reuter, in PEDOT, Principles and Applications of an Intrinsically Conductive Polymer (CRC Press, 2010), pp. 113166.
15.
15. H. T. Nicolai, M. Kuik, G. A. H. Wetzelaer, B. de Boer, C. Campbell, C. Risko, J. L. Bredas, and P. W. M. Blom, Nat. Mater. 11(10), 882887 (2012).
http://dx.doi.org/10.1038/nmat3384
16.
16. A. J. Kronemeijer, E. H. Huisman, I. Katsouras, P. A. van Hal, T. C. T. Geuns, P. W. M. Blom, S. J. van der Molen, and D. M. de Leeuw, Physical Review Letters 105(15) (2010).
http://dx.doi.org/10.1103/PhysRevLett.105.156604
17.
17. B. Smitha, S. Sridhar, and A. A. Khan, Journal of Membrane Science 259 (1–2), 1026 (2005).
http://dx.doi.org/10.1016/j.memsci.2005.01.035
18.
18. J. O. M. Bockris, A. K. N. Reddy, and M. E. Gamboa-Aldeco, Modern electrochemistry, 2nd ed. (Plenum Press, New York, 1998).
19.
19. M. A. Vorotyntsev, J. P. Badiali, and G. Inzelt, Journal of Electroanalytical Chemistry 472(1), 719 (1999).
http://dx.doi.org/10.1016/S0022-0728(99)00253-3
20.
20. R. Hass, J. Garcia-Canadas, and G. Garcia-Belmonte, Journal of Electroanalytical Chemistry 577(1), 99105 (2005).
http://dx.doi.org/10.1016/j.jelechem.2004.11.020
21.
21. K. Aoki, T. Aramoto, and Y. Hoshino, Journal of Electroanalytical Chemistry 340(1–2), 127135 (1992).
http://dx.doi.org/10.1016/0022-0728(92)80293-D
22.
22. T. Johansson, N.-K. Persson, and O. Inganäs, Journal of the Electrochemical Society 151(4), E119E124 (2004).
http://dx.doi.org/10.1149/1.1649749
23.
23. X. Wang and E. Smela, The Journal of Physical Chemistry C 113(1), 369381 (2008).
http://dx.doi.org/10.1021/jp809092d
24.
24. E. Stavrinidou, P. Leleux, H. Rajaona, D. Khodagholy, J. Rivnay, M. Lindau, S. Sanaur, and G. G. Malliaras, Adv. Mater. 25 (32), 44884493 (2013).
http://dx.doi.org/10.1002/adma.201301240
25.
25. E. Stavrinidou, P. Leleux, H. Rajaona, M. Fiocchi, S. Sanaur, and G. G. Malliaras, J. Appl. Phys. 113(24) (2013).
http://dx.doi.org/10.1063/1.4812236
26.
26. J. C. Lacroix, K. Fraoua, and P. C. Lacaze, Journal of Electroanalytical Chemistry 444(1), 8393 (1998).
http://dx.doi.org/10.1016/S0022-0728(97)00561-5
27.
27. F. Miomandre, M. N. Bussac, E. Vieil, and L. Zuppiroli, Chemical Physics 255(2–3), 291300 (2000).
http://dx.doi.org/10.1016/S0301-0104(00)00073-2
28.
28. X. Wang, B. Shapiro, and E. Smela, The Journal of Physical Chemistry C 113(1), 382401 (2008).
http://dx.doi.org/10.1021/jp802941m
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/content/aip/journal/adva/4/1/10.1063/1.4863297
2014-01-23
2014-12-17

Abstract

We monitor the process of dedoping in a planar junction between an electrolyte and a conducting polymer using electrochemical impedance spectroscopy performed during moving front measurements. The impedance spectra are consistent with an equivalent circuit of a time varying resistor in parallel with a capacitor. We show that the resistor corresponds to ion transport in the dedoped region of the film, and can be quantitatively described using ion density and drift mobility obtained from the moving front measurements. The capacitor, on the other hand, does not depend on time and is associated with charge separation at the moving front. This work offers a physical description of the impedance of conducting polymer/electrolyte interfaces based on materials parameters.

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Scitation: A physical interpretation of impedance at conducting polymer/electrolyte junctions
http://aip.metastore.ingenta.com/content/aip/journal/adva/4/1/10.1063/1.4863297
10.1063/1.4863297
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