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/content/aip/journal/adva/5/10/10.1063/1.4935186
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http://aip.metastore.ingenta.com/content/aip/journal/adva/5/10/10.1063/1.4935186
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/content/aip/journal/adva/5/10/10.1063/1.4935186
2015-10-30
2016-12-07

Abstract

The transport diffusion in one-dimensional molecular systems is investigated through non-equilibrium molecular dynamics and Monte Carlo methods. We have proposed the power law relationship of the transport diffusion coefficient with the temperature, the mass and the transport length, * * *−1 * , where equals to 0.8 for small systems and zero for large systems. It is found that Fick’s law is valid in long transport length but invalid in short transport length. Our results can provide a new perspective for understanding the microscopic mechanism of the molecular transport phenomena in low-dimensional systems.

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