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Evolution of dielectric and ferroelectric relaxor states in Al3+
1.B Jaffe, WR Cook, Jr, and H Jaffe, Piezoelectric Ceramics (Chapter 7) (Academic Press, New York, 1971).
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In ferroelectric BaTiO3, we report the evolution of the Dielectric
Relaxor and Ferroelectric Relaxor states as a function of B-site doped Al3+ concentration. The relaxor states occur after the paraelectric-ferroelectric phase transition upon cooling. Two different mechanisms are proposed; one based on migration of oxygen vacancies for symmetry-confirmation and the other based on disruption of long-range ferroelectric order by high concentrations of Al3+ ions at the B-site.
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