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1.C. S. Johnson, N. Li, C. Lefief, and M. M. Thackeray, Electrochem. Commun. 9, 787 (2007).
2.G. Singh, R. Tomas, A. Kumar, and R. S. Katiyar, J. Electrochem. Soc. 159, A410 (2012).
3.J. Shojan, C. V. Rao, L. Torres, G. Singh, and R. S. Katiyar, Mater. Lett. 104, 57 (2013).
4.D. Kim, G. Sandi, F. R. Croy, K. G. Gallagher, S. H. Kang, E. Lee, M. D. Slater, C. S. Johnson, and M. M. Thackeray, J. Electrochem. Soc. 160, A31 (2013).
5.J. S. Kim, C. S. Johnson, J. T. Vaughey, and M. M. Thackeray, Chem.Mater. 16, 1996 (2004).
6.A. Van der Ven, G. Ceder, M. Asta, and P. D. Tepesch, Phys. Rev. B 64, 184307 (2001).
7.A. Van der Ven, J. C. Thomas, Q. Xu, B. Swoboda, and D. Morgan, phys. Rev. B 78, 104304 (2008).
8.A. Van Der Ven, J. Bhattacharya, and A. A. Belak, Acc. Chem. Res. 46, 1216 (2013).
9.K. Kang and G. Ceder, Phys. Rev. B 74, 094105 (2006).
10.Z. Lu and J. R. Dahn, J. Electrochem. Soc. 149(7), A815 (2002).
11.R. Shunmugasundaram, R. S. Arumugam, and J. R. Dahn, Chem. Mater. DOI:10.1021/cm504583y.
12.H. K. Mao, J. Xu, and P. M. Bell, Geophys. Res. 91, 4673 (1986).
13.A. P. Hammersley, S. O. Svensson, M. Hanfland, A. N. Fitch, and D. Hausermann, High press. Res. 14, 235 (1996).
14.A. C. Larson and R. B. V. Dreele, Los Alamos National Laboratory Report LAUR, pp. 86748, 1994.
15.B. H. Toby, J. Appl. Crystallogr. 34, 210 (2001).
16.M. Gu, L. Belharouak, J. M. Zheng, H. M. Wu, J. Xiao, A. Genc, and C. M. Wang, ACS nano 7, 760 (2013).
17.A. Boulineau, L. Simonin, J. F. Colin, C. Bourbon, and S. Patous, nano Lett. 13, 3857 (2013).
18.Z. Li, F. Du, X.F. Bie, D. Zhang, Y.M. Cai, X.R. Cui, and C. Z. Wang, J. Phys. Chem. C 114, 22751 (2010).
19.W. C. West, J. Soler, and B. V. Ratnakumar, J. Power Sources 204, 200 (2012).
20.B. Xu, C. R. Fell, M. F. Chi, and Y. S. Meng, Energy Environ.Sci. 4, 2223 (2011).
21.D. Mohanty, A. Huq, E. A. Payzant, A. S. Sefat, J. L. Lin, D. P. Abraham, D. L. Wood, and C. Daniel, Chem. Mater. 25, 4064 (2013).
22.J. A. Speer, inCarbonates: Mineralgoy and Chemistry, edited by R. J. Reeder. (Reviews in Mineralogcal Society of America, Washington DC, 1983), p. 145.
23.C. R. Fell, D. H. Lee, Y. S. Meng, J. M. Gallardo-Amores, E. Moran, and M. E. Arroyo-de Dompablo, Energy. Environ. Sci. 5, 6214 (2012).
24.Z. H. Lu, Z. H. Chen, and J. R. Dahn, Chem. Mater. 15, 3214 (2003).
25.T. Ohzuku, M. Nagayama, K. Tsuji, and K. Ariyoshi, J. Mater. Chem. 21, 10179 (2011).
26.C. M. Lin, K. L. Lin, Y. K. Chern, C. H. Hsu, H. S. Sheu, Y. F. Liaoand, and Y. W. Suen, J. Alloys Compd. 604, 298 (2014).
27.T. Zhang and Z. S. Guo, Modelling Simul. Mater. Sci. Eng. 22, 025016 (2014).
28.C. Delmas, I. Saadoune, and A. Rougier, J. Power Sources 43, 595 (1993).
29.A. Ito, D. C. Li, Y. Sato, M. Arao, M. Watanabe, M. Hatano, H. Horie, and Y. Ohsawa, J. Power Sources 195, 567 (2010).
30.N. Yabuuchi, K. Yoshii, S. T. Myuang, I. Nakai, and S. Komaba, J. Am. Chem. Soc. 133, 4404 (2011).
31.A. C. Larson and R. B. Von Dreele, General Structure Analysis System Los Alamos National Laboratory Report LAUR 86-748, 1994{}.
32.O. L. Aderson, Equation of state of Solids for Geophysics and Ceramic Science (Oxford University, New York, 1995).

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Li-rich cathode material Li[Li Ni Mn]O was synthesized by a sol-gel method. The morphology and -NaFeO type structure of the material at ambient conditions were characterized by transmission electron microscopy (TEM) and X-ray diffraction (XRD). The high-pressure behavior of the material was studied at pressure up to 19.7 GPa by using angle dispersive synchrotron X-ray powder diffraction (ADXD). The studies affirmed that the -NaFeO type structure existed up to at least 19.7 GPa. Rietveld refinement analysis indicated that the / lattice parameter ratio decreased and the Li-O bond length shrunk with the increasing pressure, however, the Li+/Ni2+ ions exchange increased under elevated pressure. The pressure-volume data of the material were fitted to the third-order Birch-Murnaghan equation of state and bulk modulus obtained upon compression from the fitting was 117 (1) GPa.


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