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Stoichiometric controlling of boroncarbonitride thin films with using BN-C dual-targets
5.L.S. Panchakarla, K.S. Subrahmanyam, S.K. Saha, A. Govindaraj, H.R. Krishnamurthy, U. V Waghmare, and C.N.R. Rao, Advanced Materials 21, 4726 (2009).
7.N. Kumar, K. Moses, K. Pramoda, S.N. Shirodkar, A.K. Mishra, U. V. Waghmare, A. Sundaresan, and C.N.R. Rao, Journal of Materials Chemistry A 1, 5806 (2013).
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High carbon-rich boroncarbonitride thin films have been grown by pulsed laser deposition
(PLD) technique with using BN-C dual-targets. Fourier-transform infrared (FTIR)
spectroscopy results presented B-N, B-C and C-N bonds, indicating the as-deposited thin films were new ternary compounds. B-N, B-C and C-N bonding structures were also detected by X-ray photoelectron spectroscopy
(XPS), and carbon content fell into a large range of 45.8 to 85.9%. The films exhibited good thermalstability in vacuum, whereas were oxidized at 600 oC in air.
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