Skip to main content

News about Scitation

In December 2016 Scitation will launch with a new design, enhanced navigation and a much improved user experience.

To ensure a smooth transition, from today, we are temporarily stopping new account registration and single article purchases. If you already have an account you can continue to use the site as normal.

For help or more information please visit our FAQs.

banner image
No data available.
Please log in to see this content.
You have no subscription access to this content.
No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
The full text of this article is not currently available.
/content/aip/journal/adva/6/4/10.1063/1.4947121
1.
1.J.A. Turner, Science 285, 687 (1999).
http://dx.doi.org/10.1126/science.285.5428.687
2.
2.Allen J. Bard and Marye Anne Fox, Acc. Chem. Res. 28, 141 (1995).
http://dx.doi.org/10.1021/ar00051a007
3.
3.Laurence M. Peter and K.G. Upul Wijayantha, Chem. Phys. Chem.in press (2014).
4.
4.Akihiko Kudo, Kazuhiro Ueda, Hideki Kato, and Ikko Mikami, Catal. Lett. 53, 229 (1998).
http://dx.doi.org/10.1023/A:1019034728816
5.
5.Sean P. Berglund, David W. Flaherty, Nathan T. Hahn, Allen J. Bard, and C. Buddie Mullins, J. Phys. Chem. C 115, 3794 (2011).
http://dx.doi.org/10.1021/jp1109459
6.
6.Fatwa F. Abdi, Nienke Firet, and Roel van de Krol, ChemCatChem 5, 490 (2013).
http://dx.doi.org/10.1002/cctc.201200472
7.
7.Akihiko Kudo, Keiko Omori, and Hideki Kato, J. Am. Chem. Soc. 121, 11459 (1999).
http://dx.doi.org/10.1021/ja992541y
8.
8.Fatwa F. Abdi and Roel van de Krol, J. Phys. Chem. C 116, 9398 (2012).
http://dx.doi.org/10.1021/jp3007552
9.
9.Shigeru Kohtani, Kazuhiro Yoshida, Toshiyasu Maekawa, Akihide Iwase, Akihiko Kudo, Hideto Miyabe, and Ryoichi Nakagaki, Phys. Chem. Chem. Phys. 10, 2986 (2008).
http://dx.doi.org/10.1039/b719913a
10.
10.Y. Park, K.J. McDonald, and K.S. Choi, Chem. Soc. Rev. 42, 2321 (2013).
http://dx.doi.org/10.1039/C2CS35260E
11.
11.Wenjun Luo, Zaisan Yang, Zhaosheng Li, Jiyuan Zhang, Jianguo Liu, Zongyan Zhao, Zhiqiang Wang, Shicheng Yan, Tao Yu, and Zhigang Zou, Energy Env. Sci. 4, 4046 (2011).
http://dx.doi.org/10.1039/c1ee01812d
12.
12.Fatwa F. Abdi, Lihao Han, Arno H. M. Smets, Miro Zeman, Bernard Dam, and Roel van de Krol, Nature Comm. 4, 2195 (2013).
http://dx.doi.org/10.1038/ncomms3195
13.
13.Tae Woo Kim and Kyoung-Shin Choi, Science Express 343, 990 (2014).
14.
14.Le Chen, Esther Alarcón-Lladó, Mark Hettick, Ian D. Sharp, Yongjing Lin, Ali Javey, and Joel W. Ager, J. Phys. Chem. C 117, 21635 (2013).
http://dx.doi.org/10.1021/jp406019r
15.
15.Le Chen, Francesca M. Toma, Jason K. Cooper, Alan Lyon, Yongjing Lin, Ian D. Sharp, and Joel W. Ager, Chem. Sus. Chem. 8, 1066 (2015).
http://dx.doi.org/10.1002/cssc.201402984
16.
16.Le Chen, Michael E. Graham, Gonghu Li, and Kimberly A. Gray, Thin Solid Films 515, 1176 (2006).
http://dx.doi.org/10.1016/j.tsf.2006.07.094
17.
17.Yongqi Liang, Toshiki Tsubota, Lennard P. A. Mooij, and Roel van de Krol, J. Phys. Chem. C 115, 17594 (2011).
http://dx.doi.org/10.1021/jp203004v
18.
18.Weifeng Yao, Hideo Iwai, and Jinhua Ye, Dalton Trans. 1426 (2008).
http://dx.doi.org/10.1039/b713338c
19.
19.Wan-Jian Yin, Su-Huai Wei, Mowafak M. Al-Jassim, John Turner, and Yanfa Yan, Phys. Rev. B 83, 155102 (2011).
http://dx.doi.org/10.1103/PhysRevB.83.155102
20.
20.Hye Won Jeong, Tae Hwa Jeon, Jum Suk Jang, Wonyong Choi, and Hyunwoong Park, J. Phys. Chem. 117, 9102 (2013).
21.
21.J.E. Mahan and A. Vantomme, Phys. Rev. B 61(12), 8516 (2000).
http://dx.doi.org/10.1103/PhysRevB.61.8516
22.
22.G.M. Turner, I.S. Falconer, B.W. James, and D.R. McKenzie, J. Vac. Sci. Techn. A 10(3), 455 (1992).
http://dx.doi.org/10.1116/1.578171
23.
23.M. Mayer, Nucl. Instr. Meth. Phys. Res. B 194, 177 (2002).
http://dx.doi.org/10.1016/S0168-583X(02)00689-4
24.
24.Hen Dotan, Kevin Sivula, Michael Grätzel, Avner Rothschild, and Scott C. Warren, Energy Env. Sci. 4, 958 (2011).
http://dx.doi.org/10.1039/C0EE00570C
http://aip.metastore.ingenta.com/content/aip/journal/adva/6/4/10.1063/1.4947121
Loading
/content/aip/journal/adva/6/4/10.1063/1.4947121
Loading

Data & Media loading...

Loading

Article metrics loading...

/content/aip/journal/adva/6/4/10.1063/1.4947121
2016-04-14
2016-12-10

Abstract

Photoactive bismuth vanadate (BiVO) thin films were deposited by reactive co-magnetron sputtering from metallic Bi and V targets. The effects of the V-to-Bi ratio, molybdenumdoping and post-annealing on the crystallographic and photoelectrochemical (PEC) properties of the BiVOfilms were investigated. Phase-pure monoclinic BiVOfilms, which are more photoactive than the tetragonal BiVO phase, were obtained under slightly vanadium-rich conditions. After annealing of the Mo-doped BiVOfilms, the photocurrent increased 2.6 times compared to undoped films. After optimization of the BiVOfilm thickness, the photocurrent densities (without a catalyst or a blocking layer or a hole scavenger) exceeded 1.2 mA/cm2 at a potential of 1.23 V under solar AM1.5 irradiation. The surprisingly high injection efficiency of holes into the electrolyte is attributed to the highly porous film morphology. This co-magnetron sputtering preparation route for photoactive BiVOfilms opens new possibilities for the fabrication of large-scale devices for water splitting.

Loading

Full text loading...

/deliver/fulltext/aip/journal/adva/6/4/1.4947121.html;jsessionid=5JJrF7kUBrcxzcwVG3i2MaNR.x-aip-live-02?itemId=/content/aip/journal/adva/6/4/10.1063/1.4947121&mimeType=html&fmt=ahah&containerItemId=content/aip/journal/adva
true
true

Access Key

  • FFree Content
  • OAOpen Access Content
  • SSubscribed Content
  • TFree Trial Content
752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
/content/realmedia?fmt=ahah&adPositionList=
&advertTargetUrl=//oascentral.aip.org/RealMedia/ads/&sitePageValue=aipadvances.aip.org/6/4/10.1063/1.4947121&pageURL=http://scitation.aip.org/content/aip/journal/adva/6/4/10.1063/1.4947121'
Right1,Right2,Right3,