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155Gd Mössbauer spectroscopy and neutronpowderdiffraction have been used to study magnetic ordering in GdIrBi and GdIrSb. Despite the hyperfine fields (B) at the two Gd sites differing by more than a factor of two for both compounds, the moments derived from neutron diffraction are essentially equal in GdIrBi. This implies an unusual departure from the commonly assumed scaling between B and . Neutronpowderdiffraction shows that GdIrBi is a -axis ferromagnet at 3.6 K. We find no evidence for a FM → AF transition.


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