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Direct write of copper-graphene composite using micro-cold spray
M. Paunovic and C. H. Ting, in Electroless Deposition of metals and Alloys, edited byM. Paunovic and I. Ohno, Proceedings Vol. 12 (Electrochemical Society, Pennington, NJ, 1988), p. 170.
M. Paunovic and C. Stack, in Electrocrystallization, edited byR. Weil and R, G. Baradas, Proceedings Vol. 6 (Electrochemical Society, Pennington, NJ, 1981), p. 205.
R.A. Sailer et al., Micro Cold Spray Direct Write Systems and Methods for Printed Micro Electronics (2013).
S. Bhattacharya et al., “Micro Cold Spray Direct Write Process,” in ASME International Mechanical Engineering Congress and Exposition, Houston, Texas, USA (2012).
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Direct write of a new class of composite materials containing copper and graphene in the powder phase is described. The composite was synthesized using batch electroless plating of copper for various times onto Nano Graphene Platelets (NGP) to control the amount of copper deposited within the loosely aggregated graphene
Copper deposition was confirmed by both Focused Ion Beam
(FIB) and Auger electron spectroscopic analysis. A micro-cold spray technique was used to deposit traces that are ∼230 μm wide and ∼5 μm thick of the formulated copper/graphene powder onto a glass substrate. The deposited traces were found to have good adhesion to the substrate with ∼65x the copper bulk resistivity.
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