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The unsubstituted copper phthalocyanine (CuPc) single crystal nano columns were fabricated for the first time as chlorine (Cl) gas sensors in this paper. The nano columns of CuPc have been prepared on different substrates template-free physical vapor deposition (PVD) approach. The growth mechanism of CuPc nano column on quartz was explored and the same condition used on other substrates including glass, sapphire (C-plane<0001>, M-plane<>, R-plane<>), Si and SiO/Si came to a same conclusion, which confirmed that the aligned growth of CuPc nano column is not substrate-dependent. And then the CuPc nano column with special morphology was integrated as in-situ sensor device which exhibits high sensitivity and selectivity towards Cl at room temperature with a minimum detection limit as low as 0.08 ppm. The response of sensor was found to increase linearly with the increase for Cl within concentration range . These results clearly demonstrate the great potential of the nano column growth and device integration approach for sensor device.


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