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Correlation between near infrared-visible absorption, intrinsic local and global sheet resistance of poly(3,4-ethylenedioxy-thiophene) poly(styrene sulfonate) thin films
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/content/aip/journal/apl/100/15/10.1063/1.3697402
2012-04-09
2014-09-20

Abstract

The ordinary dielectric function of poly(3,4-ethylenedioxy-thiophene) poly(styrene sulfonate) (PEDOT:PSS) thin films was measured using a combination of spectroscopicellipsometry and photothermal deflection spectroscopy. This method combination allows for a highly sensitive optical characterization of thin films. Hence, even the detection of weak sub-bandgap and intra-band absorptions is enabled. These intraband transitions of free charge carriers were modeled using a Drude-type oscillator to derive an intrinsic resistances for PEDOT:PSS. These optically derived resistances were compared with those determined by a 4-probe measurement setup for two different types of PEDOT:PSS and for varied annealing temperatures. Good agreement between optical and electrical measurements could be obtained for annealing temperatures smaller than . Therefore, we conclude that the proposed combination of our two optical methods is well suited to determine electrical resistances of organic layers.

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Scitation: Correlation between near infrared-visible absorption, intrinsic local and global sheet resistance of poly(3,4-ethylenedioxy-thiophene) poly(styrene sulfonate) thin films
http://aip.metastore.ingenta.com/content/aip/journal/apl/100/15/10.1063/1.3697402
10.1063/1.3697402
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