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Anisotropic oxidation of bismuth nanostructures: Evidence for a thin film allotrope of bismuth
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10.1063/1.3701166
/content/aip/journal/apl/100/15/10.1063/1.3701166
http://aip.metastore.ingenta.com/content/aip/journal/apl/100/15/10.1063/1.3701166
View: Figures

Figures

Image of FIG. 1.
FIG. 1.

Bi(110) allotropes: (a) bulk-like (A7); (b) BP-like; (c) bulk-like after constrained optimisation; (d) BP-like after constrained optimisation; and (e) combination of structures A7 and BP. The bulk and BP-like structures are discussed in detail in Refs. 1, 9, and 12.

Image of FIG. 2.
FIG. 2.

SEM image showing a multilayer graphene flake lifted off the HOPG substrate along with as-deposited Bi islands in the background.

Image of FIG. 3.
FIG. 3.

XPS spectra recorded on a Bi(111) film (#1), Bi (110) nanostructures (#2), Bi (110) nanostructures exposed to L of dry air (1 s exposure – #3) and to L of air (5 days exposure – #4). Excitation energy is 600 eV. The dashed lines illustrate small peak shifts between the various spectra.

Image of FIG. 4.
FIG. 4.

HR-TEM micrograph showing part of a typical island (exposed to L of oxygen) with atomic resolution. Inset shows magnified image of the metallic part of the island. Surface bonds and unit cell ( nm2) have been added for sake of clarity.

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/content/aip/journal/apl/100/15/10.1063/1.3701166
2012-04-10
2014-04-20
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Anisotropic oxidation of bismuth nanostructures: Evidence for a thin film allotrope of bismuth
http://aip.metastore.ingenta.com/content/aip/journal/apl/100/15/10.1063/1.3701166
10.1063/1.3701166
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