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Transforming graphite to nanoscale diamonds by a femtosecond laser pulse
14. J. Chen, G. Conache, M. Pistol, S. Gray, M. T. Borgström, H. Xu, H. Q. Xu, L. Samuelson, and U. Håkanson, Nano Lett. 10, 1280 (2010).
16. R. Nüske, C. V. K. Schmising, A. Jurgilaitis, H. Enquist, H. Navirian, P. Sondhauss, and J. Larsson, Rev. Sci. Instrum. 81, 013106 (2010).
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Formation of cubic diamond from graphite following irradiation by a single, intense, ultra-short laser pulse has been observed. Highly oriented pyrolytic graphite (HOPG) samples were irradiated by a 100 fs pulse with a center wavelength of 800 nm. Following laser exposure, the HOPG samples were studied using Raman spectroscopy of the sample surface. In the laser-irradiated areas, nanoscale cubic diamond crystals have been formed. The exposed areas were also studied using grazing incidence x-raypowderdiffraction showing a restacking of planes from hexagonal graphite to rhombohedral graphite.
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