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High efficiency organic solar cells with spray coated active layers comprised of a low band gap conjugated polymer
12. L. Chen, Z. Hong, W. L. Kwan, C. Lu, Y. Lai, B. Lei, C. Liu, and Y. Yang, ACS Nano, 4, 4744 (2010).
14. Y. Li, W. Nie, J. Liu, A. Partridge, and D. L. Carroll, IEEE. J. Sel. Top. Quantum Electron. 1, 99 (2010).
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Airbrush is a promising tool for large scale organic thin film deposition in photovoltaic devices fabrication. This paper reports a detailed study on solar cell performance using airbrush spray deposition for active layer composed with recently developed low band gap donor material poly[4,8-bis(1-pentylhexyloxy)benzo[1,2-b:4,5-b′]dithiophene-2,6-diyl-alt-2,1,3-benzoxadiazole-4,7-diyl and [6,6]-phenyl-C61-butyric acid methyl ester. The effect of carrier solvent and substrate temperature on film morphology are studied; a formula in 1,2-dichlorobenzene sprayed at a substrate temperature of 80 °C is found to be the optimum condition that produces a peak power conversion efficiency of 5.8%.
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