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Enhanced external quantum efficiency in an organic photovoltaic cell via singlet fission exciton sensitizer
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/content/aip/journal/apl/101/11/10.1063/1.4752445
2012-09-12
2014-08-29

Abstract

We demonstrate bilayer organic photovoltaic cells that incorporate a singlet exciton fission sensitizer layer to increase the external quantum efficiency (EQE). This solar cell architecture is realized by pairing the singlet exciton donor layer tris[4-(5-phenylthiophen-2-yl)phenyl]amine (TPTPA) with the singlet exciton fission layer 5,6,11,12-tetraphenylnaphthacene (rubrene). The presence of the rubrene layer at the donor-acceptor interface allows for a singlet generated in TPTPA to undergo singlet exciton fission with a corresponding doubling in the TPTPA EQE from 12.8% to 27.6%. This scheme de-couples singlet exciton fission from photon absorption, exciton diffusion, and charge transport for very high EQE organic photovoltaic cells.

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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Enhanced external quantum efficiency in an organic photovoltaic cell via singlet fission exciton sensitizer
http://aip.metastore.ingenta.com/content/aip/journal/apl/101/11/10.1063/1.4752445
10.1063/1.4752445
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