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Micro-textured conductive polymer/silicon heterojunction photovoltaic devices with high efficiency
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/content/aip/journal/apl/101/3/10.1063/1.4734240
2012-07-16
2014-08-22

Abstract

In this work, hybrid heterojunction solar cells are demonstrated based on a conjugate polymer poly(3,4-ethylenedioxy-thiophene):poly(styrenesulfonate) (PEDOT:PSS) directly spun-cast on micro-textured n-type crystalline silicon wafers. The fabrication conditions suggest that the organic coverage on the micro-textured surface is excellent and key to achieve high efficiency, leading to an average power conversion efficiency of 9.84%. A one-dimensional drift-diffusion model is then developed based on fitting the device characteristics with experimentally determined PEDOT:PSS parameters and projects an ultimate efficiency above 20% for organic/inorganic hybrid photovoltaics. The simulation results reveal the impacts of defect densities, back surface recombination, doping concentration, and band alignment.

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Scitation: Micro-textured conductive polymer/silicon heterojunction photovoltaic devices with high efficiency
http://aip.metastore.ingenta.com/content/aip/journal/apl/101/3/10.1063/1.4734240
10.1063/1.4734240
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