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/content/aip/journal/apl/101/9/10.1063/1.4749807
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/content/aip/journal/apl/101/9/10.1063/1.4749807
2012-08-30
2016-02-09

Abstract

We report mechanoluminescence (ML) in Sm3+-doped Srn+1SnnO3n+1 (n = 1, 2, ∞) phosphors with perovskite-related structures, which consist of layered units depending on the number of n. The intensity of the ML was strongly dependent on the layered structure; the ML intensity for Sr3Sn2O7:Sm3+ was three orders of magnitude higher than that for SrSnO3:Sm3+. The charge transfer state (CTS) band in the photoluminescence excitation spectra was observed for Sr3Sn2O7:Sm3+ and Sr2SnO4:Sm3+, indicating that the efficient energy transfers from the host to the Sm3+ ions. The formation of CTS and the layered structure may be responsible for this ML enhancement.

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