AIP Publishing manuscript submission and processing system (PXP) is currently unavailable to users in China. We are working to resolve the issue as quickly as possible. We apologize for the inconvenience.

尊敬的中国作者和评审人:AIP Publishing (AIP出版公司)的论文发布系统(PXP)目前遇到一些技术问题。我们将为您尽快解决。因此带来的不便,我们向您表达我们诚挚的歉意!

Thank you for your patience during this process.

banner image
No data available.
Please log in to see this content.
You have no subscription access to this content.
No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
The full text of this article is not currently available.
1.See for general reviews, Spin Crossover in Transition Metal Compounds I-III, Topics in Current Chemistry Special Topic Vols. 233–235, edited by P. Gütlich and H. A. Goodwin (Springer, 2004).
2. S. Decurtins, P. Gütlich, C. P. Köher, H. Spiering, and A. Hauser, Chem. Phys. Lett. 105, 1 (1984).
3. A. Hauser, Chem. Phys. Lett. 124, 543 (1986).
4. E. Freysz, S. Montant, S. Létard, and J.-F. Létard, Chem. Phys. Lett. 394, 318 (2004).
5. S. Bonhommeau, G. Molnár, A. Galet, A. Zwick, J.-A. Real, J. J. McGarvey, and A. Bousseksou, Angew. Chem., Int. Ed. 44, 4069 (2005).
6. K. Binder and D. P. Landau, Phys. Rev. B 30, 1477 (1984).
7. Th. Forestier, A. Kaiba, S. Pechev, D. Denux, Ph. Guionneau, C. Etrillard, N. Daro, E. Freysz, and J.-F. Létard, Chem. - Eur. J. 15, 6122 (2009).
8. A. Bousseksou, G. Molnar, L. Salmon, and W. Nicolazzi, Chem. Soc. Rev. 40, 3313 (2011).
9. R. Bertoni, M. Lorenc, A. Tissot, M. Servol, M. L. Boillot, and E. Collet, Ang. Chem., Int. Ed. 51, 7485 (2012).
10. J. Kröber, J.-P. Audire, R. Claude, E. Codjovi, O. Kahn, J. G. Haasnoot, F. Grolire, C. Jay, A. Bousseksou, J. Linars, F. Varret, and A. Gonthier-Vassal, Chem. Mater. 6, 1404 (1994).
11. E. Coronado, J. R. Galn-Mascars, M. Monrabal-Capilla, J. Garca-Martnez, and P. Pardo-Ibez, Adv. Mater. 19, 1359 (2007).
12. S. Titos-Padilla, J. M. Herrera, X.-W. Chen, J. J. Delgado, and E. Colacio, Angew. Chem., Int. Ed. 50, 3290 (2011).
13. C. Etrillard, Ph.D. thesis, Université Bordeaux 1, 20 December 2011.
14. G. Galle, D. Deldique, J. Degert, Th. Forestier, J. F. Létard, and E. Freysz, Appl. Phys. Lett. 96, 041907 (2010).
15. O. Fouché, J. Degert, G. Jonusauskas, N. Daro, J. F. Létard, and E. Freysz, Phys. Chem. Chem. Phys. 12, 3044 (2010).
16. Y. A. Tobon, C. Etrillard, O. Nguyen, J.-F. Létard, V. Faramarzi, J.-F. Dayen, B. Doudin, D. M. Bassani, and F. Guillaume, Eur. J. Inorg. Chem. 2012, 5837.

Data & Media loading...


Article metrics loading...



We have studied the low spin to high spin phase transition induced by nanosecond laser pulses outside and within the thermal hysteresis loop of the [Fe(Htrz)2 trz](BF4)2-H2O spin crossover nanoparticles. We demonstrate that, whatever the temperature of the compound, the photo-switching is achieved in less than 12.5 ns. Outside the hysteresis loop, the photo-induced high spin state remains up to 100 μs and then relaxes. Within the thermal hysteresis loop, the photo-induced high spin state remains as long as the temperature of the sample is kept within the thermal loop. A Raman study indicates that the photo-switching can be completed using single laser pulse excitation.


Full text loading...

This is a required field
Please enter a valid email address

Oops! This section, does not exist...

Use the links on this page to find existing content.

752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Study of the fast photoswitching of spin crossover nanoparticles outside and inside their thermal hysteresis loop