1887
banner image
No data available.
Please log in to see this content.
You have no subscription access to this content.
No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
The full text of this article is not currently available.
f
Study of the fast photoswitching of spin crossover nanoparticles outside and inside their thermal hysteresis loop
Rent:
Rent this article for
Access full text Article
/content/aip/journal/apl/102/6/10.1063/1.4792527
1.
1.See for general reviews, Spin Crossover in Transition Metal Compounds I-III, Topics in Current Chemistry Special Topic Vols. 233–235, edited by P. Gütlich and H. A. Goodwin (Springer, 2004).
2.
2. S. Decurtins, P. Gütlich, C. P. Köher, H. Spiering, and A. Hauser, Chem. Phys. Lett. 105, 1 (1984).
http://dx.doi.org/10.1016/0009-2614(84)80403-0
3.
3. A. Hauser, Chem. Phys. Lett. 124, 543 (1986).
http://dx.doi.org/10.1016/0009-2614(86)85073-4
4.
4. E. Freysz, S. Montant, S. Létard, and J.-F. Létard, Chem. Phys. Lett. 394, 318 (2004).
http://dx.doi.org/10.1016/j.cplett.2004.07.017
5.
5. S. Bonhommeau, G. Molnár, A. Galet, A. Zwick, J.-A. Real, J. J. McGarvey, and A. Bousseksou, Angew. Chem., Int. Ed. 44, 4069 (2005).
http://dx.doi.org/10.1002/anie.200500717
6.
6. K. Binder and D. P. Landau, Phys. Rev. B 30, 1477 (1984).
http://dx.doi.org/10.1103/PhysRevB.30.1477
7.
7. Th. Forestier, A. Kaiba, S. Pechev, D. Denux, Ph. Guionneau, C. Etrillard, N. Daro, E. Freysz, and J.-F. Létard, Chem. - Eur. J. 15, 6122 (2009).
http://dx.doi.org/10.1002/chem.200900297
8.
8. A. Bousseksou, G. Molnar, L. Salmon, and W. Nicolazzi, Chem. Soc. Rev. 40, 3313 (2011).
http://dx.doi.org/10.1039/c1cs15042a
9.
9. R. Bertoni, M. Lorenc, A. Tissot, M. Servol, M. L. Boillot, and E. Collet, Ang. Chem., Int. Ed. 51, 7485 (2012).
http://dx.doi.org/10.1002/anie.201202215
10.
10. J. Kröber, J.-P. Audire, R. Claude, E. Codjovi, O. Kahn, J. G. Haasnoot, F. Grolire, C. Jay, A. Bousseksou, J. Linars, F. Varret, and A. Gonthier-Vassal, Chem. Mater. 6, 1404 (1994).
http://dx.doi.org/10.1021/cm00044a044
11.
11. E. Coronado, J. R. Galn-Mascars, M. Monrabal-Capilla, J. Garca-Martnez, and P. Pardo-Ibez, Adv. Mater. 19, 1359 (2007).
http://dx.doi.org/10.1002/adma.200700559
12.
12. S. Titos-Padilla, J. M. Herrera, X.-W. Chen, J. J. Delgado, and E. Colacio, Angew. Chem., Int. Ed. 50, 3290 (2011).
http://dx.doi.org/10.1002/anie.201007847
13.
13. C. Etrillard, Ph.D. thesis, Université Bordeaux 1, 20 December 2011.
14.
14. G. Galle, D. Deldique, J. Degert, Th. Forestier, J. F. Létard, and E. Freysz, Appl. Phys. Lett. 96, 041907 (2010).
http://dx.doi.org/10.1063/1.3294312
15.
15. O. Fouché, J. Degert, G. Jonusauskas, N. Daro, J. F. Létard, and E. Freysz, Phys. Chem. Chem. Phys. 12, 3044 (2010).
http://dx.doi.org/10.1039/b921984f
16.
16. Y. A. Tobon, C. Etrillard, O. Nguyen, J.-F. Létard, V. Faramarzi, J.-F. Dayen, B. Doudin, D. M. Bassani, and F. Guillaume, Eur. J. Inorg. Chem. 2012, 5837.
http://dx.doi.org/10.1002/ejic.201200562
http://aip.metastore.ingenta.com/content/aip/journal/apl/102/6/10.1063/1.4792527
Loading
/content/aip/journal/apl/102/6/10.1063/1.4792527
Loading

Data & Media loading...

Loading

Article metrics loading...

/content/aip/journal/apl/102/6/10.1063/1.4792527
2013-02-13
2014-10-23

Abstract

We have studied the low spin to high spin phase transition induced by nanosecond laser pulses outside and within the thermal hysteresis loop of the [Fe(Htrz)2 trz](BF4)2-H2O spin crossover nanoparticles. We demonstrate that, whatever the temperature of the compound, the photo-switching is achieved in less than 12.5 ns. Outside the hysteresis loop, the photo-induced high spin state remains up to 100 μs and then relaxes. Within the thermal hysteresis loop, the photo-induced high spin state remains as long as the temperature of the sample is kept within the thermal loop. A Raman study indicates that the photo-switching can be completed using single laser pulse excitation.

Loading

Full text loading...

/deliver/fulltext/aip/journal/apl/102/6/1.4792527.html;jsessionid=39umvh61snccc.x-aip-live-02?itemId=/content/aip/journal/apl/102/6/10.1063/1.4792527&mimeType=html&fmt=ahah&containerItemId=content/aip/journal/apl
true
true
This is a required field
Please enter a valid email address
752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Study of the fast photoswitching of spin crossover nanoparticles outside and inside their thermal hysteresis loop
http://aip.metastore.ingenta.com/content/aip/journal/apl/102/6/10.1063/1.4792527
10.1063/1.4792527
SEARCH_EXPAND_ITEM