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Origins of nanostructure in amorphous polymer coatings via matrix assisted pulsed laser evaporation
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10.1063/1.4821366
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    Affiliations:
    1 Department of Chemical and Biological Engineering, School of Engineering and Applied Sciences, Princeton University, Princeton, New Jersey 08544, USA
    2 Department of Mechanical and Aerospace Engineering, School of Engineering and Applied Sciences, Princeton University, Princeton, New Jersey 08544, USA
    3 Princeton Institute for the Science and Technology of Materials, Princeton University, Princeton, New Jersey 08544, USA
    a) Author to whom correspondence should be addressed. Electronic mail: rpriestl@princeton.edu
    Appl. Phys. Lett. 103, 123105 (2013); http://dx.doi.org/10.1063/1.4821366
/content/aip/journal/apl/103/12/10.1063/1.4821366
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Figures

Image of FIG. 1.
FIG. 1.

AFM phase images of PMMA films formed after (a) 2.5 min, (b) 10 min, and (c) 40 min of MAPLE deposition time. (d) Histogram plot of nanoglobule radius for five deposition times.

Image of FIG. 2.
FIG. 2.

AFM phase images of PMMA films MAPLE deposited from (a) 0.05%, (b) 0.1%, (c) 0.5%, and (d) 1.0% PMMA by weight target solutions. (e) Histogram plot of nanoglobule radius for four target concentrations.

Image of FIG. 3.
FIG. 3.

(a) Histogram plot of number of mers per nanoglobule for 0.05% (dotted red curve) and 0.1% (solid bluecurve) MAPLE-deposited films, compared with N scaling. (b) Schematic of nanoglobule formation from MAPLE-ejected polymer/solvent clusters. Equal sized clusters with different polymer concentrations will form differently sized nanoglobules after evaporation.

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/content/aip/journal/apl/103/12/10.1063/1.4821366
2013-09-17
2014-04-17
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Origins of nanostructure in amorphous polymer coatings via matrix assisted pulsed laser evaporation
http://aip.metastore.ingenta.com/content/aip/journal/apl/103/12/10.1063/1.4821366
10.1063/1.4821366
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