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/content/aip/journal/apl/105/3/10.1063/1.4891181
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/content/aip/journal/apl/105/3/10.1063/1.4891181
2014-07-23
2016-09-30

Abstract

We report a simple method to mitigate ultra-violet (UV) degradation in TiO based perovskite solar cells (PSC) using a transparent luminescent down-shifting (DS) YVO:Eu3+ nano-phosphor layer. The PSC coated with DS phosphor showed an improvement in stability under prolonged illumination retaining more than 50% of its initial efficiency, whereas PSC without the phosphor layer degraded to ∼35% of its initial value. The phosphor layer also provided ∼8.5% enhancement in photocurrent due to DS of incident UV photons into additional red photons. YVO:Eu3+ layer thus served a bi-functional role in PSC by reducing photo-degradation as well as enhancing energy conversion efficiency.

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