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Raman band contours for water vapor as a function of temperature
1.M. Lapp, AIAA Paper No. 74–1143, 1974; AIAA J. (to be published).
2.C. M. Penney and M. Lapp, J. Opt. Soc. Am. (to be published).
3.R. Goulard, in Laser Raman Gas Diagnostics, edited by M. Lapp and C. M. Penney (Plenum, New York, 1974), pp. 3–14;
3.also, J. Quant. Spectrosc. Radiat. Transfer 14, 969 (1974).
4.G. Herzberg, Molecular Spectra and Molecular Structure II. Infrared and Raman Spectra of Polyatomic Molecules (Van Nostrand, Princeton, N.J., 1945), p. 489.
5.R. Gaufrès, C. Acad. Sci. B 277, 297 (1973);
5.see also S. Sportouch, R. J. H. Clark, and R. Gaufrès, J. Raman Spectrosc. 2, 153 (1974).
6.W. F. Murphy, Fourth International Conference on Raman Spectroscopy, Brunswick, Maine, 1974 (unpublished).
7.In Ref. 4, p. 53.
8.C. Camy‐Peyret and J. M. Flaud, thesis (Université P. et M. Curie, Paris VI, 1975) (unpublished), No. AO 11443;
8.C. Camy‐Peyret, J. M. Flaud, and J. P. Maillard, Mol. Phys. (to be published).
9.D. M. Gates, R. F. Calfee, D. W. Hansen, and W. S. Benedict, N.B.S. Monograph 71 (1964).
10.J. M. Flaud and C. Camy‐Peyret, J. Mol. Spectrosc. 51, 142 (1974).
11.For water vapor over the temperature range considered here, density could also be monitored by observation of the integrated Raman contour intensity, which is constant with temperature because of the low population of excited vibrational levels. However, experimental circumstances exist for which it is desirable to use a narrower spectral passband, as is suggested here. At elevated temperatures, the integrated Raman contour intensity can vary with temperature and, for a molecule such as water, can span a spectral interval inconveniently wide for accurate integrated intensity measurements.
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