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Spin selective x‐ray absorption spectroscopy: Demonstration using high resolution Fe Kβ fluorescence
1.B. E. Warren, X-Ray Diffraction (Dover, New York, 1990).
2.D. B. McWhan, J. B. Hastings, C. C. Kao, and D. P. Siddons, Rev. Sci. Instrum. 63, 1404 (1992).
3.D. B. McWhan, NSLS Newsletter, July, 6 (1993).
4.B. T. Thole, P. Carra, F. Sette, and G. van der Laan, Phys. Rev. Lett. 68, 1943 (1992);
4.P. Carra, Synchrotron Rad. News 5, 21 (1992).
5.G. Schütz, R. Frahm, P. Mautner, R. Wienke, W. Wagner, W. Wilhelm, and P. Kienle, Phys. Rev. Lett. 62, 2620 (1989).
6.K. Hämäläinen, C. C. Kao, J. B. Hastings, D. P. Siddons, L. E. Berman, V. Stojanoff, and S. P. Cramer, Phys. Rev. B 46, 14274 (1992).
7.V. Stojanoff, K. Hämäläinen, D. P. Siddons, J. B. Hastings, L. E. Berman, S. P. Cramer, and G. Smith, Rev. Sci. Instrum. 63, 1125 (1992).
8.N. S. Gill, J. Chem. Soc. 3512 (1961).
9.J. A. Bearden and A. F. Burr, Rev. Mod. Phys. 39, 125 (1967).
10.X-ray Data Booklet, edited by D. Vaughan, Lawrence Berkeley Lab Pub-490, University of California, Berkeley, 1986.
11.D. Coster and M. Druyvesteyn, Z. Phys. 40, 765 (1927).
12.K. Tsutsumi, J. Phys. Soc. Jpn. 14, 1696 (1959);
12.K. Tsutsumi, J. Phys. Soc. Jpn. 25, 1418 (1968).
13.B. Ekstig, E. Kallne, E. Noreland, and R. Manne, Phys. Scr. 2, 38 (1970). Other explanations for the structure are reviewed in this reference.
14.V. I. Nefedov, Bull. Acad. Sci. USSR. Phys. Ser. 2, 724 (1964);
14.V. I. Nefedov, J. Struct. Chem. 7, 672 (1966).
15.The ligand field atomic multiplet calculations used to simulate the emission spectra for Fe(III) used a initial state and final states. Hartree-Fock calculations were used to evaluate the and coulomb integrals ( ), which were reduced to 80% of their calculated atomic values, while the exchange integrals and which determine the main peak and satellite splitting, were reduced to 55%. To describe the local symmetry a ligand field splitting was included. The spectra were convoluted with Lorentzians of 1.5 or 3 eV FWHM (for and regions, respectively) and with a Gaussian of to describe the lifetime and instrumental broadening, respectively.
16.G. Peng, F. M. F. deGroot, K. Hämäläinen, J. A. Moore, X. Wang, M. M. Grush, J. B. Hastings, D. P. Siddons, W. H. Armstrong, O. C. Mullins, and S. P. Cramer, J. Am. Chem. Soc. 116, 2914 (1994).
17.G. Schütz, Phys. Scr. T 29, 172 (1989).
18.G. Schütz, R. Frahm, P. Mautner, R. Wienke, W. Wagner, W. Wilhelm, and P. Kienle, Phys. Rev. Lett. 62, 2620 (1989).
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