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Analysis of the intermolecular interaction of nanocomposites by THz spectroscopy
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10.1063/1.1811795
/content/aip/journal/apl/85/18/10.1063/1.1811795
http://aip.metastore.ingenta.com/content/aip/journal/apl/85/18/10.1063/1.1811795

Figures

Image of FIG. 1.
FIG. 1.

The calculated results of the real and the imaginary part of the dielectric function of PA-66, PA-6, PA-6 nanocomposite and PA-6 microcomposite films. The top figure shows the real part of the dielectric function and the bottom shows the imaginary one. Extreme differences of the slope in the dielectric function of PA-6 nanocomposite compared with other polymers were observed.

Image of FIG. 2.
FIG. 2.

Fourier transform infrared ATR spectra of PA-66, PA-6, PA-6 nanocomposite and PA-6 microcomposite films. The top figure shows the NH stretching region, and the bottom figure shows the Amide I and Amide II regions.

Image of FIG. 3.
FIG. 3.

The correlation between the relaxation time calculated from the THz spectra and the IR peak position. Each figure shows the correlation with NH stretching mode, Amide I band, Amide II band, and combination band of Amide I and Amide II mode.

Tables

Generic image for table
Table I.

The calculated results of the static dielectric constant , high frequency limit of the dielectric function , and the relaxation time from the reflection and the transmission THz spectra by applying the Debye formula. The IR peak positions of the characteristic band were also summarized.

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/content/aip/journal/apl/85/18/10.1063/1.1811795
2004-11-03
2014-04-25
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Analysis of the intermolecular interaction of nanocomposites by THz spectroscopy
http://aip.metastore.ingenta.com/content/aip/journal/apl/85/18/10.1063/1.1811795
10.1063/1.1811795
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