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Proposed radical chain mechanism for the insertion of groups in gas phase molecules.
Proposed molecular structure of a stable gas phase cyclic adduct.
(Color) Results of the fluid dynamic simulations of a vertical MOCVD axial symmetric reactor: (a) Temperature field and streamlines, (b) gas phase mole fraction, (c) gas phase mole fraction, (d) mole fraction computed using the kinetic scheme reported in Table I.
Gas phase kinetic mechanism. In Reactions (11) and (14), is either 0 or 1 depending on the overall stoichiometry. Kinetic constants expressed as . Activation energies are reported in kcal∕mol, and the logarithm of pre-exponential factors are reported in for bimolecular reactions and in for unimolecular reaction [Reaction (3), (7), (15)]. All reactions are considered irreversible except for Reaction (2).
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