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Molecular structures for (a) pf1cnp1, (b) pf3cnp1, and (c) pftpaq.
PL enhancements for (a) pf1cnp1, (b) pf3cnp1, and (c) pftpaq on metal (dashed line) and without metal (solid line). (d) PL enhancement ratios plotted against the wavelength.
(a) Underlying physical mechanism cartoon depiction. (b) Surface plasmon dispersion diagram, polymer interfaced with Au (dashed line), Ag (solid line), and Al (dotted line).
TRPL with the data normalized to 1 where the dotted line show the conjugated polymer carrier decay rate with metal and solid line without metal, (a) pf1cnp1, (b) pf3cnp1, and (c) pftpaq. (d) Average Purcell factor, comparing the carrier lifetime, plotted against the wavelength for the conjugated polymers studied.
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