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Thickness dependent ion conductivity of lithium borate network glasses
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View: Figures


Image of FIG. 1.
FIG. 1.

Cross section through a borate glass layer embedded between two crystalline Al(Li) electrodes in the (a) as-prepared state and (b) after annealing for at .

Image of FIG. 2.
FIG. 2.

(a) Nyquist diagram of the specific resistivity of two glass films with (●) Al(Li) electrodes and (엯) electrodes. (b) The capacity per unit area of the films is found to be a linear function of the inverse glass thickness.

Image of FIG. 3.
FIG. 3.

Arrhenius representation of the ionic conductivity of sputtered glass films. Results obtained during the first and second heating cycle are shown for a rather thick and a very thin layer .

Image of FIG. 4.
FIG. 4.

Ionic conductivities for glassy borate films of varying thickness in comparison to a glass produced from the melt. In each case, the stable conductivity after the first annealing cycle is shown.

Image of FIG. 5.
FIG. 5.

Ionic conductivity at plotted vs the layer thickness. The solid line represents a fit according to the space charge model.


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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Thickness dependent ion conductivity of lithium borate network glasses