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Anchoring phthalocyanine molecules on the surface
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10.1063/1.2769761
/content/aip/journal/apl/91/7/10.1063/1.2769761
http://aip.metastore.ingenta.com/content/aip/journal/apl/91/7/10.1063/1.2769761
View: Figures

Figures

Image of FIG. 1.
FIG. 1.

STM image of individual molecules on recorded at a sample bias and a tunnel current .

Image of FIG. 2.
FIG. 2.

(Color online) (a) Typical molecule topography. , . (b) The associated adsorption model shows the molecule and the top two Silicon layers of the surface (adatoms and trimers).

Image of FIG. 3.
FIG. 3.

(Color online) Adsorption model of the phthalocyanine molecule showing the electronic rearrangement. Two silicon DB’s of the SiC surface form covalent Si–N bonds with two conjugated nitrogen atoms of the molecule.

Image of FIG. 4.
FIG. 4.

(Color online) Top and two side views of the optimized configuration of the unit cluster.

Image of FIG. 5.
FIG. 5.

(Color online) STM topography showing a tip induced motion of a molecule during the scan. , . A discontinuity is visible in the middle of the topography (a). The corresponding molecule positions in the lower and upper parts of the topography are schematized in (b) and (c) showing a rotation around the Si2–N bond.

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/content/aip/journal/apl/91/7/10.1063/1.2769761
2007-08-13
2014-04-19
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Anchoring phthalocyanine molecules on the 6H‐SiC(0001)3×3 surface
http://aip.metastore.ingenta.com/content/aip/journal/apl/91/7/10.1063/1.2769761
10.1063/1.2769761
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