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Fluorine containing derivatives for high-performance electron transporting field-effect transistors and integrated circuits
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Figures

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FIG. 1.

Chemical structures of the fluorine containing fullerene derivatives 1–4.

Image of FIG. 2.

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FIG. 2.

UV-vis absorption spectra of the fluorine containing fullerene derivatives 1–4 in solution.

Image of FIG. 3.

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FIG. 3.

Output characteristics for a type I (a) and a type II (b) transistors based on 1. The channel dimensions for the type I device are and . For the type II transistor , . Insets: schematic structures of type I (a) and type II (b) transistors tested.

Image of FIG. 4.

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FIG. 4.

(a) Micrograph of the seven-stage ring oscillator based on type II transistors employing as the design rule. (b) Oscillation frequency vs for a seven-stage ring oscillator based on 1. Inset: output signal at .

Tables

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Table I.

Performance parameters of transistors based on fullerene derivatives 1–4.

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/content/aip/journal/apl/92/14/10.1063/1.2907348
2008-04-10
2014-04-20

Abstract

We report on electron transporting organic transistors and integrated ring oscillators based on four different solution processible fluorine containing derivatives. Electron mobilities up to are obtained from as-prepared bottom-gate, bottom-contact transistors utilizing gold source-drain electrodes. Despite the high mobility, no long-range structural order could be identified with the semiconductor films exhibiting amorphouslike characteristics. The good electron transport is attributed to the structural symmetry of the fullerene derivatives and the enhanced interactions between units even in the case of amorphouslike films. These advantageous characteristics make fluorine containing derivatives attractive for application in high-performance, large-area organic electronics.

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Scitation: Fluorine containing C60 derivatives for high-performance electron transporting field-effect transistors and integrated circuits
http://aip.metastore.ingenta.com/content/aip/journal/apl/92/14/10.1063/1.2907348
10.1063/1.2907348
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