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General in situ chemical etching synthesis of ZnO nanotips array
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18. is a polar molecule and there exists a lone pair of electrons in its electronic structure leading to an asymmetry of the positive and negative charge centers. Because ZnO surface is also negatively/positively charged, the negative/positive charge on the nanowire surface will attract the polar molecules of The density of the absorbed molecules varies with the locations on the sharp nanowire due to the fact that the higher the curvature, the higher the electrostatic adhesion. For a sharp nanowire, the tipmost area has the highest curvature and thus can attract more molecule compared with other areas.
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