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Element- and site-specific oxidation state and cation distribution in manganese ferrite films by diffraction anomalous fine structure
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10.1063/1.2969406
/content/aip/journal/apl/93/5/10.1063/1.2969406
http://aip.metastore.ingenta.com/content/aip/journal/apl/93/5/10.1063/1.2969406

Figures

Image of FIG. 1.
FIG. 1.

(a) Mn edge DAFS for the (422) and (222) Bragg reflections, together with EXAFS data. The scans are vertically shifted to allow comparison. (b) Fourier transformed Mn and Fe EXAFS data plotted with best fit data.

Image of FIG. 2.
FIG. 2.

Energy shift plotted as a function of coordination charge for various (a) Fe and (b) Mn oxide standards together with site-specific values for the Mn-ferrite films studied here [denoted by (hkl), A/B site].

Image of FIG. 3.
FIG. 3.

Measured and calculated magnetization vs temperature data under an applied magnetic field of 5000 Oe. Calculation was based on molecular field theory.

Tables

Generic image for table
Table I.

Structural properties determined from best fits of fluorescence EXAFS, and DAFS spectra measured at (422) and (222) Bragg peaks. The error bars in the least significant digit are given in parentheses.

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/content/aip/journal/apl/93/5/10.1063/1.2969406
2008-08-08
2014-04-20
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Element- and site-specific oxidation state and cation distribution in manganese ferrite films by diffraction anomalous fine structure
http://aip.metastore.ingenta.com/content/aip/journal/apl/93/5/10.1063/1.2969406
10.1063/1.2969406
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