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Organic photovoltaic cells made from sandwich-type rare earth phthalocyaninato double and triple deckers
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This work presents organic-inorganichybridsolar cells, which possess the capability for broad band photon harvesting from an ultraviolet-visible to a near infrared range. These solar cells are bulk heterojunction devices, which have been fabricated by free base phthalocyanine and rare earth phthalocyaninato double or triple deckers (electron donors) with a perylenediimide derivative (electron acceptor). Two-type cell structures with or without nanostructured layers have been presented. A characterization of the structures, steady state spectroscopy, fluorescence dynamics, and photoelectrical property of these cells and the active materials has been carried out. A cell structure of -active material- has shown a significant improvement in conversion efficiency.
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