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Indium tin oxide modified transparent nanotube thin films as effective anodes for flexible organic light-emitting diodes
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Sn-doped (ITO) modified single-walled carbon nanotube (SW-CNT) transparent electrodes are fabricated on flexible polyethyleneterephthalate (PET) substrates by stamp printing SW-CNT films, followed by room temperature ion-assisted deposition of ITO. Polymer light-emitting diodes(PLEDs) using such film as anodes exhibit superior performance versus CNT-only controls. Flexible PLEDs with the following structure: PET/CNT(30 nm)-ITO(45 nm)/poly (3,4-ethylenedioxythiophene) poly (styrenesulfonate)/[poly(9,9-dioctyl-fluorene-co-N-(4-butylphenyl)diphenylamine)]+-bis[(p-trichlorosilyl propylphenyl)-phenylamino]biphenyl}/[poly(9,9-dioctylfluorene-co-benzothiadiazole)]/CsF/Al, achieve a maximum light output of with a current efficiency of . Bending test comparisons with ITO/PET show the ITO modified CNT/PET electrodes to be far more mechanically flexible.
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