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Dye-sensitized solar cells consisting of dye-bilayer structure stained with two dyes for harvesting light of wide range of wavelength
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FIG. 1.

Fabrication process of DSC-2-TiO and image of light-harvesting with wide range of wavelength. A: glass; B: F doped ; BD: black dye, NK3705 (see experimental section); and CD process: pressurized condition.

Image of FIG. 2.

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FIG. 2.

Photovoltaic properties of DSCs. DSC-2-TiO-BD-NK: BD-staining under a pressurized ; condition: 18 MPa, , 80 min; NK-staining condition: dipping for 3 h; DSC-1-TiO-BD: dipping for 20 h; DSC-1-TiO-NK: dipping for 3 h, AM1.5, .

Image of FIG. 3.

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FIG. 3.

IPCE curves for bilayer cell and single-layer cells. Dye-staining condition: see Fig. 2.

Image of FIG. 4.

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FIG. 4.

Relationship between fluorescence-intensity and distance from glass surface in layer. Dye-bilayer structure was observed by monitoring fluorescent from each dye using a confocal laser microscope. See text in detail. Excitation: 408 nm; observation: 485–540 nm; Z907 adsorption: 5 MPa, , 60 min; NK3705 adsorption: dipping for 3 h.

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/content/aip/journal/apl/93/9/10.1063/1.2976677
2008-09-03
2014-04-25

Abstract

Dye-sensitized solar cells (DSCs) containing dye-bilayer structure of black dye and NK3705 (3-carboxymethyl-5-[3-(4-sulfobutyl)-2(3H)-bezothiazolylidene]-2-thioxo-4-thiazolidinone, sodium salt) in one layer (2-TiO-BD-NK) are reported. The 2-TiO-BD-NK structure was fabricated by staining one layer with these two dyes, step by step, under a pressurized condition. The dye-bilayer structure was observed by using a confocal laser scanning microscope. The short circuit current and the incident photon to current efficiency of the cell (DSC-2-TiO-BD-NK) was almost the sum of those of DSC stained with black dye only (DSC-1-TiO-BD) and DSC stained with NK3705 only (DSC-1-TiO-NK).

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Scitation: Dye-sensitized solar cells consisting of dye-bilayer structure stained with two dyes for harvesting light of wide range of wavelength
http://aip.metastore.ingenta.com/content/aip/journal/apl/93/9/10.1063/1.2976677
10.1063/1.2976677
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