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Laser direct write printing of sensitive and robust light emitting organic molecules
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FIG. 1.

Conceptualization of LDW printing mechanism (i) before and (ii) during initial stages of material transfer. (a) DMA, (b) thin MFA layer with titanium, and (c) thick PFA layers.

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FIG. 2.

PL spectra of (a) AM showing significant damage when printed via DMA but no apparent damage using either MFA or PFA approaches. An undamaged spectrum of (b) material printed via DMA transferred at higher fluences can be seen for the molecule.

Image of FIG. 3.

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FIG. 3.

NMR spectra of AM for (a) control and printed using (b) PFA , (c) MFA , and (d) DMA transfer techniques. Arrows indicate degradation products present in MFA and DMA. No peaks exist in control or PFA.

Image of FIG. 4.

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FIG. 4.

NMR spectra of for (a) control and printed using DMA at (b) , (c) , and (d) . No degradation is visible at any of these fluences.

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/content/aip/journal/apl/94/10/10.1063/1.3098375
2009-03-12
2014-04-16

Abstract

We examine the effects of three laser direct-write (LDW) printing techniques on 9-anthracenemethanol and tris(8-hydroxyquinoline)aluminum organic luminophores in order to link the differences in transfer mechanism to the resulting material properties. Degradation can occur where laser light and elevated temperatures are transferred to the molecules, such as those printed via matrix-assisted or thin metal absorptive layer LDW. In contrast, thick film polyimide absorbing layer techniques eliminate damage in these sensitive materials by shielding them from excessive heat and laser illumination.

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Scitation: Laser direct write printing of sensitive and robust light emitting organic molecules
http://aip.metastore.ingenta.com/content/aip/journal/apl/94/10/10.1063/1.3098375
10.1063/1.3098375
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