1887
banner image
No data available.
Please log in to see this content.
You have no subscription access to this content.
No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
Valence-differential spectroscopy of Co–Fe cyanide films
Rent:
Rent this article for
USD
10.1063/1.3103561
/content/aip/journal/apl/94/11/10.1063/1.3103561
http://aip.metastore.ingenta.com/content/aip/journal/apl/94/11/10.1063/1.3103561

Figures

Image of FIG. 1.
FIG. 1.

(a) Schematic illustration of valence-differential spectroscopy. (b) Relative change in the averaged valence against the number of the electric pulses, 0.25 V in height and 1 s in duration, in film.

Image of FIG. 2.
FIG. 2.

Valence-differential absorption spectra against relative change in the averaged valence in film at 300 K. Solid (broken) curves were measured in the -increasing (-decreasing) run. Inset shows relative change in absorption coefficient at 2.4 eV against . Open (closed) circles were obtained in the -increasing (-decreasing) run. Straight line is a result of least-square fitting.

Image of FIG. 3.
FIG. 3.

(a) Absorption spectrum and valence-differential absorption spectrum of film at 300 K around the CN stretching mode. The absorption band indicated by is due to the CN stretching mode within . (b) and spectra of film at 300 K around the CN stretching mode. (c) and spectra of film at 300 K. (d) and spectra of film at 300 K. Solid curves in the lower panel of (c) and (d) represent decomposition of the spectrum with four Gaussian functions.

Tables

Generic image for table
Table I.

Transition energy , width , and oscillator strength of film and film.

Loading

Article metrics loading...

/content/aip/journal/apl/94/11/10.1063/1.3103561
2009-03-20
2014-04-24
Loading

Full text loading...

This is a required field
Please enter a valid email address
752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Valence-differential spectroscopy of Co–Fe cyanide films
http://aip.metastore.ingenta.com/content/aip/journal/apl/94/11/10.1063/1.3103561
10.1063/1.3103561
SEARCH_EXPAND_ITEM