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Molecular orientation of CuPc thin films on
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Figures

Image of FIG. 1.

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FIG. 1.

(a) Schematic drawing showing the molecular structure of CuPc. Angle-dependent N -edge NEXAFS spectra for (b) monolayer and (c) multilayer CuPc on .

Image of FIG. 2.

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FIG. 2.

(a) STM image (, ) showing the coexistence of two phases (- and -phases) of CuPc on . (b) STM image (, ) of monolayer CuPc on Ag(111). (c) STM image (, ) of -phase CuPc on , the insert (, ) showing the CuPc molecular arrangements. (d) Line profile taken along the white line drawn in panel (c), revealing that CuPc molecules do not lie flat on hcp .

Image of FIG. 3.

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FIG. 3.

(a) STM image (, ) of -phase CuPc on . (b) Line profiles taken along the lines 1, 2, and 3, as marked in panel (a), respectively. (c) A high resolution (, ) STM image of -phase CuPc on and (d) corresponding proposed model for -phase CuPc on .

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/content/aip/journal/apl/94/16/10.1063/1.3122940
2009-04-20
2014-04-16

Abstract

The molecular orientation of copper(II) phthalocyanine (CuPc) thin films on monolayer on Ag(111) was studied by in situnear-edge x-ray absorption fine structure measurements and low-temperature scanning tunneling microscopy. It is found that in densely packed thin films, CuPc molecules adopt a standing-up configuration with the molecular -plane tilting slightly from the surface normal on monolayer.

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Scitation: Molecular orientation of CuPc thin films on C60/Ag(111)
http://aip.metastore.ingenta.com/content/aip/journal/apl/94/16/10.1063/1.3122940
10.1063/1.3122940
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