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Biphase micro/nanometer sized single crystals of organic semiconductors: Control synthesis and their strong phase dependent optoelectronic properties
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Figures

Image of FIG. 1.

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FIG. 1.

The single crystal diffraction results of and phase BPEA. (a) and (b) Packing diagram, (c) and (d) molecular structure viewed along the long axis, and (e) and (f) molecular structure viewed along the short axis. (a), (c), and (e) phase ; (b), (d), and (f) phase .

Image of FIG. 2.

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FIG. 2.

(a) and (b) AFM images (inset: Cross-section along the white line), (c) and (d) TEM images, and (e) and (f) SAED patterns of an individual rod and ribbon of BPEA. (a), (c), and (e): Rod; (b), (d), and (f): Ribbon.

Image of FIG. 3.

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FIG. 3.

(a) and (b) The SEM images of an example device based on an individual single crystal micro/nanorod and ribbon of BPEA, (c) and (d) their corresponding field-effect transistor transfer curves, and (e) and (f) photoswitching characteristics of an individual micro/nanorod and ribbon devices (white light, light density , ). (a), (c), (e): Rod; (b), (d), (f): Ribbon.

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/content/aip/journal/apl/96/14/10.1063/1.3383222
2010-04-05
2014-04-20

Abstract

The control synthesis of and phase micro/nanometer sized single crystals of semiconductor 9,10-bis(phenylethynyl)anthracene were achieved; the device performance of individual and phase single crystals showed strong phase dependence; devices of phase single crystals exhibited very high photoswitch performance (on/off current ratio , one of the highest values reported for organic materials), and those of phase displayed high field-effect performance.

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Scitation: Biphase micro/nanometer sized single crystals of organic semiconductors: Control synthesis and their strong phase dependent optoelectronic properties
http://aip.metastore.ingenta.com/content/aip/journal/apl/96/14/10.1063/1.3383222
10.1063/1.3383222
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