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Interfacial electronic structure of copper hexadecafluorophthalocyanine and phthalocyanatotin (IV) dichloride studied by photoemission spectroscopy
22.W. Chen, S. Chen, S. Chen, Y. L. Huang, H. Huang, D. C. Qi, X. Y. Gao, J. Ma, and A. T. S. Wee, J. Appl. Phys. 106, 064910 (2009).
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We investigated the interfacial electronic structure of the n-n isotype organic heterojunction formed between copper hexadecafluorophthalocyanine and phthalocyanatotin (IV) dichloride using ultraviolet and x-ray photoemission spectroscopies. Energy level bending was observed at the heterojunction interface due to the formation of an electron accumulation region in the layer and an electron depletion region in the layer. The formation of organic heterojunction was explained by charge exchange at the interface due to their different work functions.
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