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Local stoichiometry in amorphous supramolecular composites analyzed by solid-state nuclear magnetic resonance
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Solid-statenuclear magnetic resonance(NMR) has been applied to “amorphous” active layers consisting of donor-acceptor self-assembled composites in organic solar cells. Several stoichiometric supramolecular complexation states as well as the charge-transfer states are revealed by the solid-stateNMR, which have been difficult to access by conventional spectroscopy. The spectra show clear correlation between local self-assembled supramolecular structures and the organic solar cell performances.
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