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PbO-deficient : Mass transport, structural effects and possibility for intrinsic screening of the ferroelectric polarization
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10.1063/1.3555336
/content/aip/journal/apl/98/9/10.1063/1.3555336
http://aip.metastore.ingenta.com/content/aip/journal/apl/98/9/10.1063/1.3555336
View: Figures

Figures

Image of FIG. 1.
FIG. 1.

(a) Lattice parameters and (b) tetragonality and unit cell volume of as a function of nominal stoichiometry. The hatched region marks the -rich border of the single phase region.

Image of FIG. 2.
FIG. 2.

Linear shrinkage of pellets during firing of a green body at for 8 h; see inset for explanation. is the molar volume of reaction of .

Image of FIG. 3.
FIG. 3.

(a) Schematic illustration of polarization in a ferroelectric thin film. (b) Possibility of charge separation due to separation of lead and oxygen vacancies, e.g., caused by an internal field. (c) Proposed mechanism for screening of depolarization field by separation of lead and oxygen vacancies and (d) epitaxial strain by a gradient in vacancy concentration.

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/content/aip/journal/apl/98/9/10.1063/1.3555336
2011-03-03
2014-04-20
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: PbO-deficient PbTiO3: Mass transport, structural effects and possibility for intrinsic screening of the ferroelectric polarization
http://aip.metastore.ingenta.com/content/aip/journal/apl/98/9/10.1063/1.3555336
10.1063/1.3555336
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