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Morphology of as-grown crystals of clinoatacamite (left), paratacamite (middle), and herbertsmithite (right).
Partial powder XRD patterns for paratacamite and clinoatacamite with radiation.
Raman spectra for the crystals of , clinoatacamite , paratacamite , and herbertsmithite , measured with excitation line.
Temperature dependence of dc susceptibility for clinoatacamite , paratacamite and herbertsmithite in the field of 20 Oe with random orientation. ZFC and FC notes zero-field-cool and field-cool measurement modes. Inset: separation of ZFC and FC indicates a magnetic phase transition of clinoatacamite at .
Structure and synthesis conditions of crystals of clinoatacamite, paratacamite, and herbertsmithite.
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