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Polymer solar cells with gold nanoclusters decorated multi-layer graphene as transparent electrode
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Figures

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FIG. 1.

(Color online) Illuminated J-V characteristics of representative MLG PSCs. Inset shows the performance of respective MLG PSCs and reference ITO/PEDOT:PSS/P3HT:PCBM/LiF/Al PSC.

Image of FIG. 2.

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FIG. 2.

(Color online) UPS spectra of different MLG samples. A: pristine MLG only, B: MLG/pre-UVO (3.5 min)/Au (2 nm) without post-UVO, C: MLG/pre-UVO (3.5 min)/Au (2 nm) with 2 min post-UVO, D: MLG/pre-UVO (3.5 min)/Au (2 nm) with 6 min post-UVO. Inset shows the performance of MLG/Au PSCs with different post-UVO time and pre-UVO/Au evaporation of 3.5 min/2 nm.

Tables

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Table I.

Performance summary of MLG/Au PSCs with different pre-UVO time and Au evaporation/post-UVO of 2 nm/2 min.

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/content/aip/journal/apl/99/22/10.1063/1.3664120
2011-11-30
2014-04-23

Abstract

A thin layer of ultraviolet-ozone (UVO) treated gold(Au) is introduced on multi-layergraphene (MLG) to enable the MLG as an effective anode for polymersolar cells (PSCs). By optimizing the Au thickness and the durations of the UVO treatments at different stages, MLG PSCs with enhanced fill factor and power conversion efficiency are obtained, exhibiting better performance compared with MLG devices directly modified with UVO and poly(3,4-ethylenedioythiophene):poly(styrenesulfonate). Further analysis shows that UVO treated Au provides favorable band alignment at the MLG/polymer interface. Moreover, the improved interfacial contact and shortened UVO durations reduce the series resistance of PSCs significantly.

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Scitation: Polymer solar cells with gold nanoclusters decorated multi-layer graphene as transparent electrode
http://aip.metastore.ingenta.com/content/aip/journal/apl/99/22/10.1063/1.3664120
10.1063/1.3664120
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