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Highly clear conductive polymer electrode films hybridized with gold nanoparticles
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1.
1. Z. Yao, H. W. Ch. Poatma, L. Balents, and C. Dekker, Nature 402, 273 (1999).
http://dx.doi.org/10.1038/46241
2.
2. D. Normile, Science 286, 2056 (1999).
http://dx.doi.org/10.1126/science.286.5447.2056b
3.
3. J. Kong, N. R. Franklin, C. Zhou, M. G. Chapline, S. Peng, K. Cho, and H. Dai, Science 287, 622 (2000).
http://dx.doi.org/10.1126/science.287.5453.622
4.
4. R. H. Baughman, C. Cui, A. A. Zakhidov, Z. J. Iqbal, N. Barisci, G. M. Spinks, G. G. Wallace, A. Mazzoldi, D. De Rossi, A. G. Rinzler, O. Jaschinski, S. Roth, and M. Kertesz, Science 284, 1340 (1999).
http://dx.doi.org/10.1126/science.284.5418.1340
5.
5. H. Sirringhaus, T. Kawase, R. H. Friend, T. Shimoda, M. Inbasekaran, W. Wu, and E. P. Wooet, Science 290, 2123 (2000).
http://dx.doi.org/10.1126/science.290.5499.2123
6.
6. J. Huang, X. Vanlaeke, W. Geens, J. Poortmans, P. Heremans, S. Borghs, R. Mertens, R. Andriessen, and L. Leenders, Thin Solid Films 22, 451 (2004).
7.
7. G. Heywang and F. Jonas, Adv. Mater. 4, 116 (1992).
http://dx.doi.org/10.1002/adma.v4:2
8.
8. F. Jonas and L. Schrader, Synth. Met. 41–43, 831 (1991).
http://dx.doi.org/10.1016/0379-6779(91)91506-6
9.
9. A. N. Aleshin, S. R. Williams, and A. J. Heeger, Synth. Met. 94, 173 (1994).
http://dx.doi.org/10.1016/S0379-6779(97)04167-2
10.
10. T. Granlund, L. A. A. Pettersson, and O. Inganäs, J. Appl. Phys. 89, 5897 (2001).
http://dx.doi.org/10.1063/1.1350998
11.
11. S. Ghosh and O. Inganäs, Synth. Met. 121, 1321 (2001).
http://dx.doi.org/10.1016/S0379-6779(00)01523-X
12.
12. Y. Gao, G. Yu, C. Zhang, R. Menon, and A. J. Heeger, Synth. Met. 87, 171 (1997).
http://dx.doi.org/10.1016/S0379-6779(97)03823-X
13.
13. J. Y. Kim, H. Y. Woo, J. W. Baek, T. W. Kim, E. A. Song, S. C. Park, and D. W. Ihm, Appl. Phys. Lett. 92, 183301 (2008).
http://dx.doi.org/10.1063/1.2905277
14.
14. K. C. Grabar, R. G. Freeman, M. B. Hommer, and M. J. Natan, Anal. Chem. 67, 735 (1995).
http://dx.doi.org/10.1021/ac00100a008
15.
15. N. Ma, H. Zhang, B. Song, Z. Wang, and X. Xhang, Chem. Mater. 17, 5065 (2005).
http://dx.doi.org/10.1021/cm051221c
16.
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FIG. 1.

(Color online) Schematic structure of metallic polymer chain hybridized with charged Au nanoparticles and charge transfer mechanism (electron transfer from charged Au NPs to conducting polymer chain and subsequently from PEDOT to Au NPs).

Image of FIG. 2.

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FIG. 2.

(Color online) PEDOT-Au hybrid film fabrication scheme using self-assembling vapor-phase polymerization and SEM* images of film surface morphologies. (I) SEM image of colloidal Au NPs deposited as the monolayer on the LbL films composed of PAH/PSS/PAH. (II) SEM image of self-assembled PEDOT hybrid layer connected between Au NPs.

Image of FIG. 3.

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FIG. 3.

(Color online) (I) The sheet resistance of the PEDOT-Au NPs hybrid layers as a function of thickness; (a) PEDOT only, (b) PEDOT-Au 3 nm NPs, (c) PEDOT-Au 5 nm NPs, (d) PEDOT-Au 9 nm NPs, and (e) PEDOT-Au 12 nm NPs hybrids, respectively. (f) Amorphous-ITO and (g) sputtered Au metal films. (II) Optical spectra for PEDOT-Au NPs hybrid films composed with 3, 5, 9, and 12 nm Au particles, respectively; (a) PEDOT only, (b) PEDOT-Au 3 nm NPs, (c) PEDOT-Au nm NPs, (d) PEDOT-Au 9 nm NPs, and (e) PEDOT-Au 12 nm NPs hybrid films.

Image of FIG. 4.

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FIG. 4.

(Color online) The device configuration of flexible OLED (left) and I-V-L characteristics curves comparing PEDOT-Au NPs hybrid anode (85 Ω sq−1) with amorphous-ITO anode (85 Ω sq−1) (right); (a) I-V curve at ITO anode, (b) I-V curve at PEDOT-Au NPs hybrid anode, (a) L-V curve at ITO anode, and (b) L-V curve at PEDOT-Au NPs hybrid anode, respectively.

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/content/aip/journal/apl/99/23/10.1063/1.3665612
2011-12-07
2014-04-24

Abstract

Improved conductive poly(3,4-ethylenedioxy thiophene) (PEDOT) electrodefilms were made through hybridization with charged gold nanoparticles. The conductivity of these hybrid films increased more than seven times than the value for the PEDOT alone. The optimized films show a sheet resistance value down to 85 ohm·sq−1 at 85% transparency when PEDOT was hybridized with gold particles of 12 nm diameter, and the organic light-emitting diode devices deposited on these electrodes show a performance equivalent to that of devices based on a conventional indium tin oxide electrode.

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Scitation: Highly clear conductive polymer electrode films hybridized with gold nanoparticles
http://aip.metastore.ingenta.com/content/aip/journal/apl/99/23/10.1063/1.3665612
10.1063/1.3665612
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