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Ideal design of textured LiCoO2
sintered electrode for Li-ion secondary battery
10. M. Hirayama, N. Sonoyama, T. Abe, M. Minoura, M. Ito, D. Mori, A. Yamada, R. Kanno, T. Terashima, M. Takano, K. Tamura, and J. Mizuki, J. Power Sources 168, 493 (2007).
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To improve the energy density and practical realization of the all-solid-state Li-ion secondary battery, the principal requirement is a high electric conductivity in the densely sintered positive electrode. To accomplish this task, we focused on the anisotropic Li-ion and electron conductivities of the LiCoO2. As a result of our work, the ideal design of the texturing, perpendicular alignment of the c-plane and horizontal but random orientation of the c-axis on the electrode, was proposed. The battery performance of the ideal textured cell fabricated using a rotating strong magnetic field has a significantly higher performance than a randomly oriented cell.
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