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A new MOF-5 homologue for selective separation of methane from C2
hydrocarbons at room temperature
3.P. Horcajada, R. Gref, T. Baati, P. K. Allan, G. Maurin, P. Couvreur, G. Férey, R. E. Morris, and C. Serre, Chem. Rev. 112, 1232–1268 (2012).
16.J. Cai, J. Yu, H. Xu, Y. He, X. Duan, Y. Cui, C. Wu, B. Chen, and G. Qian, Cryst. Growth Des. 13, 2094–2097 (2013).
21.Single-crystal X-ray crystallographic data: Fm3m, a = b = c = 21.643 Å, α = β = γ = 90°, V = 10138 Å3.
See supplementary material at http://dx.doi.org/10.1063/1.4897351
for thermal gravimetric analysis; powder X-ray diffraction patterns before and after activation; the BET and Langmuir analysis of N2
adsorption isotherms; and the Langmuir-Freundlich fits of the gas adsorption isotherms.[Supplementary Material]
27.Y. He, Z. Zhang, S. Xiang, H. Wu, F. R. Fronczek, W. Zhou, R. Krishna, M. O’Keeffe, and B. Chen, Chem. - Eur. J. 18, 1901–1904 (2012).
28.S. Xiang, Z. Zhang, C.-G. Zhao, K. Hong, X. Zhao, D.-L. Ding, M.-H. Xie, C.-D. Wu, R. Gill, K. M. Thomas, and B. Chen, Nature Commun. 2, 204 (2012).
29.H. Xu, Y. He, Z. Zhang, S. Xiang, J. Cai, Y. Cui, Y. Yang, G. Qian, and B. Chen, J. Mater. Chem. A 1, 77–81 (2013).
30.M. C. Das, Q. Guo, Y. He, J. Kim, J. C.-G. Zhao, K. Hong, S. Xiang, Z. Zhang, K. M. Thomas, R. Krishna, and B. Chen, J. Am. Chem. Soc. 134, 8703–8710 (2012).
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A new MOF-5 homologue compound UTSA-10 has been obtained under solvothermal conditions from a mixture of Zn(NO3)2⋅6H2O and commercially available linker, 2-methylfumaric acid, in N,N-dimethylformamide. The moderate surface area and suitable pore sizes enable the activated UTSA-10a to separate methane from C2 hydrocarbons at room temperature.
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