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Cerium reduction at the interface between ceria and yttria-stabilised zirconia and implications for interfacial oxygen non-stoichiometry
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/content/aip/journal/aplmater/2/3/10.1063/1.4867556
2014-03-06
2014-12-26

Abstract

Epitaxial CeO films with different thickness were grown on YO stabilised Zirconia substrates. Reduction of cerium ions at the interface between CeO films and yttria stabilised zirconia substrates is demonstrated using aberration-corrected scanning transmission electron microscopy combined with electron energy-loss spectroscopy. It is revealed that most of the Ce ions were reduced from Ce4+ to Ce3+ at the interface region with a decay of several nanometers. Several possibilities of charge compensations are discussed. Irrespective of the details, such local non-stoichiometries are crucial not only for understanding charge transport in such hetero-structures but also for understanding ceria catalytic properties.

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Scitation: Cerium reduction at the interface between ceria and yttria-stabilised zirconia and implications for interfacial oxygen non-stoichiometry
http://aip.metastore.ingenta.com/content/aip/journal/aplmater/2/3/10.1063/1.4867556
10.1063/1.4867556
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