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/content/aip/journal/aplmater/3/12/10.1063/1.4936665
1.
1.C. T. Kresge, M. E. Leonowicz, W. J. Roth, J. C. Vartuli, and J. S. Beck, Nature 359, 710 (1992).
http://dx.doi.org/10.1038/359710a0
2.
2.Y. Wan and D. Zhao, Chem. Rev. 107, 2821 (2007).
http://dx.doi.org/10.1021/cr068020s
3.
3.Y. Wan, Y. F. Shi, and D. Y. Zhao, Chem. Commun. 897 (2007).
http://dx.doi.org/10.1039/b610570j
4.
4.L. Han, K. Miyasaka, O. Terasaki, and S. Che, J. Am. Chem. Soc. 133, 11524 (2011).
http://dx.doi.org/10.1021/ja200683t
5.
5.H.-Y. Hsueh, C.-T. Yao, and R.-M. Ho, Chem. Soc. Rev. 44, 1974 (2015).
http://dx.doi.org/10.1039/C4CS00424H
6.
6.C. Yu, B. Tian, and D. Zhao, Curr. Opin. Solid State Mater. Sci. 7, 191 (2003).
http://dx.doi.org/10.1016/j.cossms.2003.10.004
7.
7.T. Kimura, Microporous Mesoporous Mater. 77, 97 (2005).
http://dx.doi.org/10.1016/j.micromeso.2004.08.023
8.
8.T. Kimura, J. Nanosci. Nanotechnol. 13, 2461 (2013).
http://dx.doi.org/10.1166/jnn.2013.7397
9.
9.T.-Y. Ma, L. Liu, and Z.-Y. Yuan, Chem. Soc. Rev. 42, 3977 (2013).
http://dx.doi.org/10.1039/C2CS35301F
10.
10.L. Han and S. Che, Chem. Soc. Rev. 42, 3740 (2013).
http://dx.doi.org/10.1039/C2CS35297D
11.
11.Z. Huang and S. Che, Bull. Chem. Soc. Jpn. 88, 617 (2015).
http://dx.doi.org/10.1246/bcsj.20140416
12.
12.B. P. Bastakoti, Y. Li, T. Kimura, and Y. Yamauchi, Small 11, 1992 (2015).
http://dx.doi.org/10.1002/smll.201402573
13.
13.Y.-J. Cheng and J. S. Gutmann, J. Am. Chem. Soc. 128, 4658 (2006).
http://dx.doi.org/10.1021/ja0562853
14.
14.Y.-J. Cheng, S. Zhou, and J. S. Gutmann, Macromol. Rapid Commun. 28, 1392 (2007).
http://dx.doi.org/10.1002/marc.200700165
15.
15.D. Chandra, M. Bekki, M. Nakamura, S. Sonezaki, T. Ohji, K. Kato, and T. Kimura, J. Mater. Chem. 21, 5738 (2011).
http://dx.doi.org/10.1039/c0jm04347h
16.
16.D. Chandra, T. Ohji, K. Kato, and T. Kimura, Phys. Chem. Chem. Phys. 13, 12529 (2011).
http://dx.doi.org/10.1039/c1cp21060b
17.
17.T. Kimura, M. Shintate, and N. Miyamoto, Chem. Commun. 51, 1230 (2015).
http://dx.doi.org/10.1039/C4CC08497G
18.
18.T. Kimura, Macromol. Rapid Commun. 34, 423 (2013).
http://dx.doi.org/10.1002/marc.201200765
19.
19.T. Kimura, J. Mater. Chem. A 2, 10688 (2014).
http://dx.doi.org/10.1039/c4ta01448k
20.
20.T. Kimura, APL Mater. 2, 113301–9 (2014).
http://dx.doi.org/10.1063/1.4897202
21.
21.T. Kimura, Chem. - Asian J. 6, 3236 (2011).
http://dx.doi.org/10.1002/asia.201100173
22.
22.T. Kimura and Y. Yamauchi, Langmuir 28, 12901 (2012).
http://dx.doi.org/10.1021/la302695q
23.
23.S. Dutta, K. C.-W. Wu, and T. Kimura, Chem. Mater. 27, 6918 (2015).
http://dx.doi.org/10.1021/acs.chemmater.5b02435
24.
24.H. G. Yang and H. C. Zeng, J. Phys. Chem. B 108, 3492 (2004).
http://dx.doi.org/10.1021/jp0377782
25.
25.J. Li and H. C. Zeng, Chem. Mater. 18, 4270 (2006).
http://dx.doi.org/10.1021/cm060362r
26.
26.R. J. Davis and Z. Liu, Chem. Mater. 9, 2311 (1997).
http://dx.doi.org/10.1021/cm970314u
27.
27.D. Sun, Y. Huang, B. Han, and G. Yang, Langmuir 22, 4793 (2006).
http://dx.doi.org/10.1021/la053172o
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/content/aip/journal/aplmater/3/12/10.1063/1.4936665
2015-12-01
2016-12-07

Abstract

A recently developed reticular type porous structure, which can be fabricated as the film through the soft colloidalblock copolymer (e.g., PS--PEO) templating, is very promising as the porous platform showing high-performance based on its high surface area as well as high diffusivity of targeted organic molecules and effective accommodation of bulky molecules, but the compositional design of oxide frameworks has not been developed so enough to date. Here, I report reliable synthetic methods of the reticular type porous structure toward simple compositional variations. Due to the reproducibility of reticular type porous titania films from titanium alkoxide (e.g., TTIP; titanium tetraisopropoxide), a titania-silica film having similar porous structure was obtained by mixing silicon alkoxide (e.g., tetraethoxysilane) and TTIP followed by their pre-hydrolysis, and the mixing ratio of Ti to Si composition was easily reached to 1.0. For further compositional design, a concept of surfacecoating was widely applicable; the reticular type porous titania surfaces can be coated with other oxides such as silica. Here, a silicacoating was successfully achieved by the simple chemical vapor deposition of silicon alkoxide (e.g., tetramethoxysilane) without water (with water at the humidity level), which was also utilized for pore filling with silica by the similar process with water.

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